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辽东湾西部海域表层沉积物重金属的含量分布与污染评价

Concentration distribution and pollution assessment of heavy metalsin surface sediments in the western waters of Liaodong Bay

  • 摘要: 对2009年春、秋两季辽东湾西部海域共25个采样站位4种重金属含量的分布特征进行了研究,并利用潜在生态风险指数法和地质累积指数法对其污染状况进行了评价.结果表明:该海域表层沉积物中Cu、Pb、Zn和Cd平均含量范围分别为8.0~32.1、4.3~56.9、20.0~102.6、0.12~0.34 mg/kg;Cu、Pb、Zn和Cd含量平均值均高于渤海重金属背景值.在该海域表层沉积物重金属单元素平均含量的潜在生态风险指数中,Cd的风险等级已经达到“中等”,Cu、Pb和Zn的潜在生态风险等级“较低”;各重金属元素综合潜在生态风险等级属于“中等”,近岸及河口等海域的生态风险等级相对较高.重金属地质累积指数评价结果显示,Cu和Zn属于0级污染,Pb和Cd属于“轻度”污染.因此,作者建议应控制该海域近岸养殖区密度和减少养殖污染.表层沉积物中重金属和TOC含量相关性分析表明:该海域表层沉积物中重金属Cu、Pb和Zn具有一定的同源性,TOC含量对重金属分布具有一定的影响.

     

    Abstract: Four heavy metalsin surfacesediments from 25 sites in the western waters of Liaodong Bay in spring andautumn of 2009 were investigated.Concentrations of copper(Cu),lead(Pb),zinc(Zn)and cadmium(Cd)insurface sediments were measured with aflame atomic absorption spectrophotometer(FAS),and thesediments werealso analyzed with FAS for quality contol.Heavy metal pollution level were evaluated with the potential ecologicalrisk index and the geo-accumulation index.The results showed that the average concentrations of Cu,Pb,Zn andCr at different siteswere 8.0~32.1,4.3~56.9,20.0~102.6,0.12~0.34 mg/kg,respectively.The concen-trationsof Cu,Pb,Zn and Cd were higher than the background values of Bohai.Thepotential ecological risk of Cdwas in middle level and Cu,Pb and Zn were low.The potential ecological risk of heavy metals was in middle leveland was higher in nearshoreand estuary.The geo-accumulation indexof Cu and Zn were in zero level,and Pb andCd were low.Wesuggests that theaquaculturedensity be controlled in aquaculture area and humanactivities ofseafanming reduced.Correlation analysisbetween heavy metals and TOCconcentation in surface sediment showed thatthe elements ofCu,Pb and Zn probably had the same pollution source and TOC concentration had influenced onthe distribution of heavy metals in surface sediments in thewestem watersof Liaodong Bay.

     

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