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CFC-12与SF6示踪的南海东北部水团运输及人为碳储量

Tracing of water mass and anthropogenic CO2 in the northeastern South China Sea traced by CFC-12 and SF6

  • 摘要: 二氯二氟甲烷(CFC-12)和六氟化硫(SF6)因其明确的人为来源性和高度保守性,是海洋中水团运输、年代测定和人为碳储量等研究的重要示踪剂,对于揭示海洋混合与气候变化过程具有重要意义。本研究于2023年8—9月系统研究了南海东北部CFC-12和SF6的空间分布及影响因素,揭示了CFC-12和SF6在南海东北部水团运输中的示踪作用,并基于运移时间分布方法估算了南海人为碳储量。分析结果表明,南海东北部表层海水中CFC-12和SF6平均浓度分别为(1.85±0.82) pmol/L和(0.88±0.48) fmol/L,均呈现北高南低、近岸高外海低的分布特征,这与陆源输入和海气扩散过程有关;CFC-12和SF6浓度最大值出现在表层,表层以下其浓度随着深度的增加而降低。吕宋海峡东西两侧CFC-12和SF6浓度的垂直剖面具有明显的梯度变化,中层水中CFC-12和SF6浓度由南海至西北太平洋递减,而深层水中则相反,这印证了吕宋海峡水团交换的“三明治结构”。南海人为碳单位面积平均储量为(37.49±7.50) mol/m2,总人为碳储量约为(0.92±0.18) Pg,增长速率为20 Tg/a,南海人为碳每年储存量约占全球排放量的0.05%。

     

    Abstract: Dichlorodifluoromethane (CFC-12) and sulfur hexafluoride (SF6) serve as important tracers due to their distinct anthropogenic sources and high conservativeness in oceanographic studies, which could indicate ocean water mass transport, dating, and anthropogenic carbon dioxide (CO2) storage. The surveys were conducted in the northeastern South China Sea (SCS) from August to September, 2023, to investigate the spatial distributions and influencing environmental parameters and to reveal the tracer role of CFC-12 and SF6 in water mass transport in the study area. Furthermore, anthropogenic CO2 storage was quantified using the transit time distribution (TTD) method in SCS. Results showed that the average concentrations of CFC-12 and SF6 are (1.85±0.82) pmol/L and (0.88±0.48) fmol/L in the surface seawater of SCS, respectively. The tracer distributions exhibited distinct spatial gradients, with concentrations decreasing progressively from northern to southern regions and from the inshore to the offshore. This spatial pattern reflected the combined influences of terrestrial input sources and air-sea exchange processes. The maximum concentrations of CFC-12 and SF6 were observed in the surface layer, and their concentrations decreased with depth monotonically below the surface layer. The vertical profiles of CFC-12 and SF6 revealed contrasting tracer gradients across the Luzon Strait, with a decreasing trend from the South China Sea to the Northwest Pacific in the intermediate water, while an opposite trend was observed in the deep water. The results confirmed that the “sandwiched vertical structure” of water mass transport in the Luzon Strait. The mean anthropogenic CO2 column inventories were estimated to be (37.49 ± 7.50) mol/m2 in the South China Sea. The total anthropogenic carbon storage in SCS was approximately (0.92 ± 0.18) Pg, with a growth rate of 20 Tg/a, which stored about 0.05% of global anthropogenic CO2 emissions annually.

     

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